A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

被引：0
作者：
Mehmet Kandaz
Seher Zerrin Çoruhlu
İsmail Yilmaz
Ali Rıza Özkaya
机构：
[1] Sakarya University,Department of Chemistry
[2] Adapazarı,Department of Chemistry
[3] Istanbul Technical University,Department of Chemistry
[4] Maslak,undefined
[5] Marmara University,undefined
[6] Kadıköy,undefined
来源：
Transition Metal Chemistry | 2002年 / 27卷
关键词：
Physical Chemistry; Inorganic Chemistry; Cyclic Voltammetry; Metal Complex; Electrochemical Property;
D O I：
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学科分类号：
摘要：
A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal–ligand ratio of 1:2. The synthesis of di- and trinuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.–vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.
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页码：877 / 883
页数：6
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