Electrochemical oxidation of organic, organometallic, and coordination compounds. Polarization effect in radical cations

被引：0
|
作者：
O. V. Novikova
O. V. Kuznetsova
A. N. Egorochkin
机构：
[1] Russian Academy of Sciences,Razuvaev Institute of Organometallic Chemistry
来源：
Russian Journal of General Chemistry | 2007年 / 77卷
关键词：
Reaction Center; General Chemistry; Glassy Carbon Electrode; Radical Cation; High Occupied Molecular Orbital;
D O I：
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中图分类号：
学科分类号：
摘要：
Half-wave potentials of electrochemical oxidation of 24 reaction series X-B-RC depend on the inductive, resonance, and polarization effects of substituents X. The polarization effect was not taken into account previously. In X-B-RC·+ radical cations, the contribution of the polarization effect increases with decreasing size of bridge B linking X with the reaction center RC and can reach 30%.
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页码：1601 / 1609
页数：8
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