Thermochemistry of binary alloys of lanthanum with 3d-transition metals

被引:0
作者
V. V. Berezutskii
N. I. Usenko
M. I. Ivanov
机构
[1] National Academy of Sciences of Ukraine,Institute for Problems of Materials Science
来源
Powder Metallurgy and Metal Ceramics | 2006年 / 45卷
关键词
lanthanum; 3d-metal; calorimetry; enthalpy; d-zone; electron structure; density of states;
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摘要
The enthalpy of mixing for liquid binary alloys of lanthanum with 3d-transition metals (Sc, Ti, V, Cr, and Fe) is determined by a calorimetric method within the field of compositions rich in lanthanum. Data for the partial enthalpy of mixing in the La-3d-metal system with infinite dilution demonstrates a complex relationship of a change in it in the series of 3d-metals connected with gradual filling of the 3d-zone due to alloy formation with lanthanum.
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页码:266 / 271
页数:5
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