Influence of nano-sized fumed silica on physicochemical and electrochemical properties of cellulose derivatives-ionic liquid biopolymer electrolytes

被引：0

作者：

M. S. A. Rani

A. Ahmad

N. S. Mohamed

机构：

[1] University of Malaya,Institute of Graduate Studies

[2] Universiti Kebangsaan Malaysia,School of Chemistry Science and Food Technology, Faculty of Science and Technology

[3] University of Malaya,Centre for Foundation Studies in Science

来源：

Ionics | 2018年 / 24卷

关键词：

Nanocomposite biopolymer electrolyte; Carboxymethyl cellulose; Ionic conductivity; Electrochemical stability; Transference number;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Nanocomposite biopolymer electrolyte was prepared by solution-casting technique. Carboxymethyl cellulose from kenaf bast fibre, ammonium acetate, (1-butyl)trimethyl ammonium bis(trifluoromethylsulfonyl)imide ionic liquid and silica nanofiller was used to prepare the biopolymer electrolyte samples. The films were characterized by Fourier transform infrared spectroscopy, electrochemical impedance spectroscopy, scanning electron microscopy, transference number measurement and linear sweep voltammetry. The interactions of doping salt, ionic liquid and inorganic nanofiller with the host biopolymer were confirmed by FTIR study. The highest conductivity achieved was 8.63 × 10−3 S cm−1 by the incorporation of 1 wt% of SiO2 at ambient temperature. The electrochemical stability of the highest conducting sample was stable up to 3.4 V, and the ion transference number in the film was 0.99.

引用

页码：807 / 814

页数：7