Electrochemical characterization of non-stoichiometric Cu2Sx cathode for lithium batteries

被引：0

作者：

Gulnur Kalimuldina

Izumi Taniguchi

机构：

[1] Tokyo Institute of Technology,Department of Chemical Engineering

[2] Tokyo Institute of Technology,Department of Chemical Science and Engineering

来源：

Journal of Solid State Electrochemistry | 2017年 / 21卷

关键词：

Copper sulfide; Chemical composition; Lithium-ion battery; Spray pyrolysis; Cathode;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Electrochemical performances of non-stoichiometric Cu2Sx (1.25 ≤ x ≤ 0.625) cathodes prepared by spray pyrolysis and followed annealing were investigated after coating on carbon fiber paper (CFP) and Cu foil current collectors. The chemical composition influence on the electrochemical properties of Cu2Sx was noticeably observed on a Cu foil current collector, especially at higher charge-discharge rates. Electrochemical impedance spectroscopy revealed that Cu/S ≈ 3.2 M ratio electrode shows lower interfacial charge transfer resistance (Rct) after 5 cycles at 0.1 C compared with Cu/S ≈ 1.6 M ratio electrode on both current collectors. Accordingly, the electrode with Cu/S ≈ 3.2 M ratio showed the highest discharge capacity of 350 mAh g−1 at 5 C on a Cu foil current collector. The excess of Cu in Cu2Sx enhanced electrode utilization with the cycle number and facilitated fast charge transfer.

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页码：3057 / 3063

页数：6

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