Crystal and molecular structure of [Cu2(3,5-dihydroxybenzoate)4 (acetonitrile)2] ⋅ 8H2O

被引：0
作者：
Giannis S. Papaefstathiou
Brett G. Darrow
Leonard R. MacGillivray
机构：
[1] University of Iowa,Department of Chemistry
来源：
Journal of Chemical Crystallography | 2002年 / 32卷
关键词：
paddle-wheel complex; hydrogen-bonding; layered structure;
D O I：
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摘要：
The crystal and molecular structure of the title compound, [Cu2(3,5-dihydroxybenzoate)4 (acetonitrile)2] ⋅ 8H2O 1, is reported. Crystal data for 1: tetragonal, space group I 4/m, a = 11.720(2) Å, c = 15.304(3) Å, V = 2102.4(6), and Dc = 1.53 g/cm3, for Z = 2. The metal and organic components crystallize to form a Cu paddle-wheel complex, of idealized D4h symmetry, that assembles in the solid-state, along with eight equivalents of water, to form a 3D hydrogen-bonded network held together by O–H ⋅⋅⋅ O hydrogens bonds. The metal complexes pack to form a 2D layered structure.
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页码：191 / 195
页数：4
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