Ruthenium- and palladium-catalyzed synthesis of polyfunctional 1,3-dienes

被引：0

作者：

B. Seiller-Delevoye

C. Bruneau

P. H. Dixneuf

机构：

[1] National Center of Scientific Research-University of Rennes,Laboratory of Coordination Chemistry and Catalysis

来源：

Russian Chemical Bulletin | 1998年 / 47卷 / 5期

关键词：

(; )-3-methylpent-2-en-4-yn-1-ol; carboxylic acids, addition; ruthenium(ii) complexes; (; )-4-acetoxy(or benzyloxy)-3-methylpenta-2,4-dienyl-(2-methyl-3-oxobut-2-yl) carbonate, reaction with C- and O-nucleophiles; (; )-3-methyl-5-formoxypenta-1,3-dien-2-yl benzoate; decarboxylation; tetrakis(triphenylphosphine)palladium;

D O I：

10.1007/BF02498160

中图分类号：

学科分类号：

摘要：

The ruthenium-catalyzed Markovnikov addition of acetic or benzoic acid to the triple bond of (E)-3-methylpent-2-en-4-yn-1-ol followed by acylation of the alcohol group in the diene formed under the action of low-toxic derivatives of carbonic and formic acids opens up a simple route to dienylic carbonates and formates. Activation of these esters by catalytic amounts of palladium(0) complexes under conditions of nucleophilic allylic substitution or decarboxylation affords functional dienes.

引用

页码：913 / 917

页数：4

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