Synthesis and characterization of platinum and palladium pyrrolidinedithiocarbamate complexes

被引：0

作者：

Laith Almazahreh

Mohammad El-khateeb

Mohammad Harb

Helmar Görls

Wolfgang Weigand

机构：

[1] Jordan University of Science and Technology,Chemistry Department

[2] King Abdulaziz University,Chemistry Department, Faculty of Science and Arts at Alkamil

[3] Friedrich-Schiller-Universtät Jena,Institut für Anorganische und Analytische Chemie

[4] Umm Al-Qura University,Chemistry Department, Faculty of Science at Qunfudah

来源：

Transition Metal Chemistry | 2013年 / 38卷

关键词：

CDCl3; PPh3; Bipy; Dithiocarbamate; Dppe;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Treatment of (PPh3)2MCl2 (M = Pd or Pt) with ammonium pyrrolidinedithiocarbamate (NH4S2CNC4H8) in a 1:1 molar ratio gave (PPh3)M(Cl)(κ2S,S-S2CNC4H8) [M = Pt (1), Pd (2)]. On the other hand, the interaction of these compounds in a 1:2 [M:L] molar ratio gave (PPh3)Pt(κS-S2CNC4H8)(κ2S,S-S2CNC4H8) (3), which contains both terminal and chelated dithiocarbamato ligands, or a yellow insoluble solid for M = Pd. The bis(diphenylphosphino)ethane platinum or palladium dichlorides [(dppe)MCl2] reacted with the same ligand to give the salts [(dppe)M(κ2S,S-S2CNC4H8)]Cl (M = Pt (4), Pd (5) which have only one chelating dithiocarbamato ligand. The new compounds were characterized by 1H-, 13C{1H}- and 31P-n.m.r. spectroscopy, mass spectrometry, elemental analysis and X-ray single crystal structure analysis.

引用

页码：377 / 383

页数：6

共 50 条

[31] Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II)
Dey, S
Jain, VK
Knoedler, A
Kaim, W
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2003, 42 (09): : 2339 - 2343
[32] Synthesis and characterization of binuclear palladium(II) and platinum(II) complexes with a bridging hydroxypyridinate ligand
Transition Met Chem, 6 (494):
[33] Synthesis and magnetochemical characterization of dithiolato nickel(III), palladium(III), and platinum(III) complexes
Larin, GM
Zvereva, GA
Rotov, AV
ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (10): : 1697 - 1701
[34] Synthesis and structures of diphosphinoamide complexes of nickel, palladium and platinum
Said, M
Hughes, DL
Bochmann, M
POLYHEDRON, 2006, 25 (04) : 843 - 852
[35] A NOVEL SYNTHESIS OF (OXODIMETHYLENEMETHANE)-PALLADIUM AND (OXODIMETHYLENEMETHANE)-PLATINUM COMPLEXES
OHSUKA, A
FUJIMORI, T
HIRAO, T
KUROSAWA, H
IKEDA, I
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (12) : 1039 - 1040
[36] Synthesis of platinum, palladium and rhodium complexes of -aminophosphine ligands
Balint, Erika
Tajti, Adam
Tripolszky, Anna
Keglevich, Gyorgy
DALTON TRANSACTIONS, 2018, 47 (14) : 4755 - 4778
[37] Synthesis and antitubercular activity of palladium and platinum complexes with fluoroquinolones
Vieira, Ligia Maria M.
de Almeida, Mauro V.
Lourenco, Maria Cristina S.
Bezerra, Flavio Augusto F. M.
Fontes, Ana Paula S.
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2009, 44 (10) : 4107 - 4111
[38] Synthesis of η1-borazine complexes of palladium and platinum
Braunschweig, Holger
Green, Helen
Radacki, Krzysztof
Uttinger, Katharina
DALTON TRANSACTIONS, 2008, (27) : 3531 - 3534
[39] SYNTHESIS AND CHARACTERIZATION OF ZEROVALENT PALLADIUM COMPLEXES
Zhen Feng XI Rui Na YANG D(?)u Man JIN Henan Institute of Chemistry
ChineseChemicalLetters, 1991, (04) : 331 - 334
[40] Synthesis and characterization of palladium (II) complexes
Mishra, A. K.
Mishra, S. B.
Manav, N.
Kaushik, N. K.
REVIEWS IN INORGANIC CHEMISTRY, 2007, 27 (06) : 449 - 458

← 1 2 3 4 5 →