Vapour-Liquid and Liquid-Solid Equilibria in the System Th(NO3)4-UO2(NO3)2-HNO3-H2O

被引：0
|
作者：
V. I. Volk
A. Yu. Vakhrushin
S. L. Mamaev
Yu. P. Zhirnov
机构：
[1] SSC A.A. Bochvar All-Russia Research Institute of Inorganic Materials (VNIINM),
[2] SSC A.A. Bochvar All-Russia Research Institute of Inorganic Materials (VNIINM),undefined
来源：
Journal of Radioanalytical and Nuclear Chemistry | 2000年 / 246卷
关键词：
Nitrate; Hexa; Liquid Phase; Nitric Acid; HNO3;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Vapour-liquid and liquid-solid equilibria were studied in the system Th(NO3)4-UO2(NO3)2-HNO3-H2O. Hexahydrate of thorium nitrate as well as hexa- and trihydrate of uranyl nitrate were supposed to be formed in this system. Empiric equations of solubility isotherms were derived for 25 °C and liquid phase densities were determined. It was established that nitric acid was salted out into the vapour phase by the nitrates present in the system both separately and simultaneously. Empiric equation was derived that describes the relationship between the HNO3 concentration of condensate and that of all liquid phase components.
引用
收藏
页码：703 / 708
页数：5
相关论文
共 50 条
  • [31] Study and modeling of the liquid-solid equilibrium of the KCl-KNO3-HCl-H2O system at 283.15 K
    Wang, Houpeng
    Zhou, Zhiyong
    Qin, Wei
    Li, Yigui
    Fei, Weiyang
    AICHE JOURNAL, 2020, 66 (01)
  • [32] Thermal behaviour of the nitrated AFm phase Ca4Al2(OH)12(NO3)2•4H2O and structure determination of the intermediate hydrate Ca4Al2(OH)12(NO3)2•2H2O
    Renaudin, G
    Rapin, JP
    Humbert, B
    François, M
    CEMENT AND CONCRETE RESEARCH, 2000, 30 (02) : 307 - 314
  • [33] Mixed Complex Salt [Cu4(SCN2H4)7(NO3)](NO3)(SO4) · 3.3H2O: Synthesis and X-Ray Diffraction Analysis
    L. A. Solov'ev
    A. D. Vasil'ev
    N. N. Golovnev
    Russian Journal of Coordination Chemistry, 2002, 28 : 587 - 592
  • [34] Thermodynamic properties of LiNO3-NaNO3-KNO3-2KNO3•Mg(NO3)2 system
    Wang, Tao
    Mantha, Divakar
    Reddy, Ramana G.
    THERMOCHIMICA ACTA, 2013, 551 : 92 - 98
  • [35] Theoretical study of the anion exchange properties and the thermal decomposition of Zn5(OH)8(NO3)2•2H2O and Zn5(OH)8(NO3)2•2NH3
    Tavares, Sergio R.
    Vaiss, Viviane S.
    Wypych, Fernando
    Leitao, Alexandre A.
    APPLIED CLAY SCIENCE, 2015, 114 : 103 - 111
  • [36] Tris(4-oxy-pyridinium)nitrato lanthanide complexes [M(4-O-C6H4NH)3(NO3)2(H2O)2][NO3] {M = La, Ce, Pr, Nd, Eu, Gd} - Synthesis, properties and structural characterization
    Anjaneyulu, O.
    Prasad, T. K.
    Swamy, K. C. Kumara
    INORGANICA CHIMICA ACTA, 2010, 363 (12) : 2990 - 2995
  • [37] Liquid-solid metastable equilibria of a quinary system Na+, K+//Cl-, SO42-, NO3--H2O at 298 K
    Zhou, Ting
    Wang, Xue-Feng
    Huang, Xue-Li
    Li, Hui
    Liu, Na
    Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities, 2015, 29 (03): : 510 - 515
  • [38] Prediction of densities of mixed organic solutions containing UO2(NO3)2 and nitric acid
    Kumar, S
    Koganti, SB
    JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY, 1998, 35 (04) : 309 - 312
  • [39] Crystal structure of [UO2(NH3)(5)]NO3 center dot NH3
    Woidy, Patrick
    Kraus, Florian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1710 - +
  • [40] Chemiluminescence of the Ce3+* ions, and the 1O2 and (1O2)2 molecular species of oxygen induced by active surface of the (NH4)2Ce(NO3)6 crystals at reduction of Ce4+ to Ce3+ by water in heterogeneous system "(NH4)2Ce(NO3)6-C6H6- H2O"
    Bulgakov, Ramil G.
    Gazeeva, Dilara R.
    Galimov, Dim I.
    JOURNAL OF LUMINESCENCE, 2017, 183 : 159 - 165
12345