On the interaction of vanadium species with meso-2,3-dimercaptosuccinic acid

被引：0
|
作者：
P. A. M. Williams
E. J. Baran
机构：
[1] Universidad Nacional de La Plata,Centro de Química Inorgánica (CEQUINOR/CONICET,UNLP), Facultad de Ciencias Exactas
来源：
Biological Trace Element Research | 2006年 / 109卷 / 2期
关键词：
2,3-Dimercaptosuccinic acid; oxovanadium(IV); vanadium (V); interactions; electronic spectra; vanadium detoxification;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The interaction of the VO2+ cation with meso-2,3-dimercaptosuccinic acid (DMSA) was investigated by electron absorption spectroscopy in aqueous solution at different pH values. The spectral behavior, complemented with a spectrophotometric titration, shows the generation of a [VO(DMSA)2]2− complex in which the oxocation interacts with two pairs of deprotonated-SH groups of the acid. It was also found that DMSA rapidly reduces VO3− to VO2+, which might be chelated by an excess of the acid. DMSA can also produce the partial reduction of a V2O5 suspension at pH=5.2. The results of this study suggest that DMSA might be a potentially useful detoxification agent for vanadium.
引用
收藏
页码：189 / 194
页数：5
相关论文
共 50 条
  • [21] MOBILIZATION OF LEAD IN MICE BY ADMINISTRATION OF MONOALKYL ESTERS OF MESO-2,3-DIMERCAPTOSUCCINIC ACID
    WALKER, EM
    STONE, A
    MILLIGAN, LB
    GALE, GR
    ATKINS, LM
    SMITH, AB
    JONES, MM
    SINGH, PK
    BASINGER, MA
    TOXICOLOGY, 1992, 76 (01) : 79 - 87
  • [22] Synthesis and Characterization of Polyacrylamides Containing meso-2,3-Dimercaptosuccinic Acid End Groups
    Ozeroglu, Cemal
    Birdal, Arzu
    ADVANCES IN POLYMER TECHNOLOGY, 2010, 29 (01) : 45 - 53
  • [23] CADMIUM MOBILIZATION BY MONOARALKYL AND MONOALKYL ESTERS OF MESO-2,3-DIMERCAPTOSUCCINIC ACID AND BY A DITHIOCARBAMATE
    JONES, MM
    SINGH, PK
    BASINGER, MA
    GALE, GR
    SMITH, AB
    PHARMACOLOGY & TOXICOLOGY, 1994, 74 (02): : 76 - 83
  • [24] Spectroscopic evidence of a bidentate-binding of meso-2,3-dimercaptosuccinic acid on silver nanoclusters
    Zaluzhna, Oksana
    Brightful, Lyndsey
    Allison, Thomas C.
    Tong, YuYe J.
    CHEMICAL PHYSICS LETTERS, 2011, 509 (4-6) : 148 - 151
  • [25] METABOLISM OF MESO-2,3-DIMERCAPTOSUCCINIC ACID IN LEAD-POISONED CHILDREN AND NORMAL ADULTS
    ASIEDU, P
    MOULTON, T
    BLUM, CB
    ROLDAN, E
    LOLACONO, NJ
    GRAZIANO, JH
    ENVIRONMENTAL HEALTH PERSPECTIVES, 1995, 103 (7-8) : 734 - 739
  • [26] The presence of lead decreases the availability of meso-2,3-dimercaptosuccinic acid for analysis in the monobromobimane assay
    Lever, SZ
    Parsons, TL
    CHEMICAL RESEARCH IN TOXICOLOGY, 1999, 12 (11) : 1057 - 1065
  • [27] Combined oral treatment with racemic and meso-2,3-dimercaptosuccinic acid for removal of mercury in rats
    Kostial, K
    RestekSamarzija, N
    Blanusa, M
    Piasek, M
    Jones, MM
    Singh, PK
    PHARMACOLOGY & TOXICOLOGY, 1997, 81 (05): : 242 - 244
  • [28] Quantification and biodegradability assessment of meso-2,3-dimercaptosuccinic acid adsorbed on iron oxide nanoparticles
    Bemowsky, S.
    Rother, A.
    Willmann, W.
    Koeser, J.
    Markiewicz, M.
    Dringen, R.
    Stolte, S.
    NANOSCALE ADVANCES, 2019, 1 (09): : 3670 - 3679
  • [29] MOBILIZATION OF CADMIUM BY LIPOSOME-ENCAPSULATED MESO-2,3-DIMERCAPTOSUCCINIC ACID IN PREEXPOSED MICE
    SRIVASTAVA, S
    GUPTA, S
    BEHARI, JR
    SRIVASTAVA, RC
    TOXICOLOGY LETTERS, 1991, 59 (1-3) : 125 - 131
  • [30] A multinuclear NMR study of the complexation of W(VI) with meso-2,3-dimercaptosuccinic acid (DMSA)
    Caldeira, MM
    Ramos, ML
    Pereira, GG
    Gil, VMS
    POLYHEDRON, 2000, 19 (02) : 193 - 197
12345