119Sn Mössbauer study of nickel–tin anodes for rechargeable lithium-ion batteries

被引：0
|
作者：
S. Naille
P. E. Lippens
F. Morato
J. Olivier-Fourcade
机构：
[1] Université Montpellier II,Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (CNRS UMR 5072)
来源：
Hyperfine Interactions | 2006年 / 167卷
关键词：
Sn Mössbauer spectrometry; lithium-ion batteries; intermetallic compounds; lithium insertion mechanism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
119Sn Mössbauer spectrometry has been carried out on Ni–Sn alloys (Ni3Sn LT, Ni3Sn2 LT and Ni3Sn4) and combined with ab initio calculations. Lithium insertion/extraction mechanisms of the most interesting compound (Ni3Sn4) have been studied from 119Sn Mössbauer measurements. The first discharge shows a plateau close to 0.0 V, which can be attributed to the formation of the Li7Sn2 alloy.
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页码：785 / 790
页数：5
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