Complexation of Palladium(II) Acetate and Acetylacetonate with Mono- and Bidentate Phosphine Ligands

被引：0
|
作者：
G. P. Belov
Z. M. Dzhabiyeva
V. A. Fastovets
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Journal of Coordination Chemistry | 2003年 / 29卷
关键词：
Methylene; Acetate; Physical Chemistry; Phosphorus; Toluene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Heat effects of complexation of Pd(CH3COO)2 and Pd(C5H7O2)2 with monophosphine Ph3P and diphosphines Ph2Р(CH2)nPPh2 (n = 1–4, 6) and (PPh2)2Fe(C5H4)2 in toluene at 50°С and P : Pd = 0.3–3 were measured using calorimetry methods. Heat of the complex formation and thus, its stability, were found to increase with elongation of methylene bond between phosphorus atoms in diphosphines.
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页码：102 / 105
页数：3
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