Influence of silica content in crosslinked PVA/PSSA_MA/Silica hybrid membrane for direct methanol fuel cell (DMFC)

In the present study, crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at different temperatures using poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA) (PVA:PSSA_MA = 1:9). The hybrid membranes were prepared by varying the TEOS content between 5 and 30 wt%. The PSSA_MA was used both as a crosslinking agent and the hydrophilic group donor (-SO3H and/or -COOH). The proton conductivity increased with up to 20 wt% TEOS, but decreased above this level, although the water content decreased with increasing TEOS content. This result suggests that the silica doped into the membrane improved the formation of proton-conduction pathways due to the absorption of molecular water. The PVA/PSSA_MA/Silica containing TEOS 20% showed both high proton conductivity (0.026 S/cm at 90°C) and low methanol permeability (5.55×10-7 cm2/s).