Synthesis and characterization of poly(2-ethylhexyl acrylate) prepared via atom transfer radical polymerization, reverse atom transfer radical polymerization and radical polymerization

被引：0
|
作者：
Haloi D.J. [1 ,2 ]
Koiry B.P. [2 ]
Mandal P. [2 ]
Singha N.K. [2 ]
机构：
[1] Zydex Industries, 25-A Gandhi Oil Mill Compound
[2] Rubber Technology Centre, Indian Institute of Technology Kharagpur
来源：
Haloi, D.J. (dhru_ba2k3@yahoo.co.in) | 2013年 / Springer卷 / 125期
关键词：
Atom transfer radical polymerization (ATRP); polymer synthesis; thermal properties;
D O I：
10.1007/s12039-013-0438-2
中图分类号：
学科分类号：
摘要：
This investigation reports a comparative study of poly(2-ethylhexyl acrylate) (PEHA) prepared via atom transfer radical polymerization (ATRP), reverse atom transfer radical polymerization (RATRP) and conventional free radical polymerization (FRP). The molecular weights and the molecular weight distributions of the polymers were measured by gel permeation chromatography (GPC) analysis. Structural characterization of the polymers was carried out by 1H NMR and MALDI-TOF-MS analyses. Thermal properties of the polymers were evaluated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The polymerization results and the thermal properties of PEHAs prepared via ATRP, RATRP and FRP were compared. [Figure not available: see fulltext.] © 2013 Indian Academy of Sciences.
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页码：791 / 797
页数：6
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