A study of the electrochemical behavior of the Ti(IV)/Ti(III) redox couple in the NaCl-KCl-NaF-K2TiF6 melt in order to optimize the electrorefining of titanium and synthesis of alloys based on this metal

被引：0
作者：
D. A. Vetrova
O. S. Kazakova
S. A. Kuznetsov
机构：
[1] Russian Academy of Sciences,Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center
来源：
Russian Journal of Applied Chemistry | 2014年 / 87卷
关键词：
Titanium Alloy; Molten Salt; Redox Couple; Potential Sweep Rate; Transfer Rate Constant;
D O I：
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中图分类号：
学科分类号：
摘要：
Temperature dependence of the standard charge-transfer rate constant was obtained in a study of the redox reaction Ti(IV) + e ⇆ Ti(III) in a (NaCl-KCl)equim-NaF(10 wt %)-K2TiF6 melt by cyclic voltammetry. The processes of titanium refining and high-temperature electrochemical syntheses of alloys on its basis can be optimized by using this dependence.
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页码：439 / 443
页数：4
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