Acetylsalicylhydroxamic acid and its cobalt(II), nickel(II), copper(II) and zinc(II) complexes

被引：0
作者：
Veysel T. Yılmaz
Fatih Yılmaz
机构：
[1] Ondokuz Mayıs University,Department of Chemistry, Faculty of Arts and Sciences
来源：
Transition Metal Chemistry | 1999年 / 24卷
关键词：
Oxygen; Copper; Spectroscopy; Zinc; Nickel;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Acetylsalicylhydroxamic acid (AcSHA) was prepared and characterized. Its pKa value was determined as 7.78. Solid metal complexes of AcSHA were also prepared and characterized by elemental analysis, electronic and i.r. spectroscopies, and by magnetic moment measurements. The shift of both hydroxamic and acetyl carbonyl vibrations to lower frequencies clearly indicates that AcSHA is bonded through oxygen atoms to the metal ions as a tridentate ligand. On the basis of the experimental data, structures for the complexes are purposed.
引用
收藏
页码：726 / 729
页数：3
相关论文
共 34 条
[1]  
Maehr T.(1971)undefined Pure Appl. Chem. 28 603-undefined
[2]  
Weisburger J.H.(1973)undefined Pharm. Rev. 25 1-undefined
[3]  
Weisburger E.K.(1992)undefined Coord. Chem. Rev. 114 169-undefined
[4]  
Kurzak B.(1978)undefined Coord. Chem. Rev. 26 281-undefined
[5]  
Kozlowski H.(1996)undefined Transition Met. Chem. 21 176-undefined
[6]  
Farkas F.(1996)undefined Transition Met. Chem 21 258-undefined
[7]  
Chatterjee B.(1997)undefined Transition Met. Chem 22 123-undefined
[8]  
Khary E.M.(1979)undefined Inorg. Chim. Acta 35 5-undefined
[9]  
Shoukry M.M.(1982)undefined Thermochim. Acta 56 15-undefined
[10]  
Khalil M.M.(1988)undefined Thermochim. Acta 127 285-undefined
1234