Tautomerism of the Thioamide Group in 4-Methyl-7-nitro-2,3,4,5-tetrahydro-1,5-benzodiazepine-2-thione

被引：0

作者：

R. Janciene

Z. Stumbreviciute

L. Pleckaitiene

B. Puodziunaite

机构：

[1] Institute of Biochemistry,

来源：

Chemistry of Heterocyclic Compounds | 2002年 / 38卷 / 6期

关键词：

4-methyl-7-nitro-2,3,4,5-tetrahydro-1,5-benzodiazepine-2-thione; thione-thiol tautomers;

D O I：

10.1023/A:1019933722956

中图分类号：

学科分类号：

摘要：

When 4-methyl-7-nitro-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one were reacted with phosphorus pentasulfide, the corresponding benzodiazepine-2-thione and its thiol tautomer were formed, which via the 2-methylmercapto derivative were converted to 4-(2-acetylhydrazino)-2-methyl-8-nitro-2,3-dihydro-1H-1,5-benzodiazepine.

引用

页码：738 / 740

页数：2