Tuning the Acidity of Montmorillonite by H3PO4-Activation and Supporting WO3 for Catalytic Dehydration of Glycerol to Acrolein

被引:0
作者
Wei Hua Yu
Bao Zhu
Dong Shen Tong
Kai Deng
Chao Peng Fu
Tian Hao Huang
Chun Hui Zhou
机构
[1] Zhijiang College,Research Group for Advanced Materials & Sustainable Catalysis (AMSC), Research Center for Clay Minerals, Breeding Base of State Key Laboratory of Green Chemistry Synthesis Technology
[2] Zhejiang University of Technology,Engineering Research Center of Non
[3] Discipline of Industrial Catalysis,metallic Minerals of Zhejiang Province
[4] College of Chemical Engineering,undefined
[5] Zhejiang University of Technology,undefined
[6] Zhejiang Institute of Geology and Mineral Resource,undefined
[7] Qing Yang Institute for Industrial Minerals,undefined
来源
Clays and Clay Minerals | 2022年 / 70卷
关键词
Acid-activation; Acrolein; Catalyst; Glycerol; Montmorillonite; WO;
D O I
暂无
中图分类号
学科分类号
摘要
Montmorillonite (Mnt)-based solid acids have a wide range of applications in catalysis and adsorption of pollutants. For such solid acids, the acidic characteristic often plays a significant role in these applications. The objective of the current study was to examine the effects of H3PO4-activation and supporting WO3 on the textural structure and surface acidic properties of Mnt. The Mnt-based solid acid materials were prepared by H3PO4 treatment and an impregnation method with a solution of ammonium metatungstate (AMT) and were examined as catalysts in the dehydration of glycerol to acrolein. The catalysts were characterized by nitrogen adsorption-desorption, powder X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, scanning electronic microscopy (SEM), X-ray photoelectron spectroscopy (XPS), diffuse reflectance ultraviolet-visible (DR UV-Vis) spectroscopy, temperature programmed desorption of NH3 (NH3-TPD), diffuse reflectance Fourier-transform infrared (DR FTIR) spectroscopy of adsorbed pyridine, and thermogravimetric (TG) analyses. The phosphoric acid treatment of Mnt created Brönsted and Lewis acid sites and led to increases in specific surface areas, porosity, and acidity. WO3 species influenced total acidity, acid strength, the numbers of Brönsted and Lewis acid sites, and catalytic performances. A high turnover frequency (TOF) value (31.2 h−1) based on a maximal 60.7% yield of acrolein was reached. The correlation of acrolein yield with acidic properties indicated that the cooperative role of Brönsted and Lewis acid sites was beneficial to the formation of acrolein and a little coke deposition (<3.3 wt.%). This work provides a new idea for the design of solid acid catalysts with cooperative Brönsted and Lewis acidity for the dehydration of glycerol.
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页码:460 / 479
页数:19
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