Synthesis and crystal structure of a cyanide-bridged one-dimensional nickel(II) complex with alternating [Ni(En)2]2+ and [Ni(CN)4]2− ions

被引:0
作者
B. Tao
H. Xia
X. Jiang
Y. F. Zhu
机构
[1] China University of Geosciences,Faculty of Material Science and Chemistry Engineering
来源
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词
Cyano; Prussian Blue; Shape Tube; Metal Cyanide; Tetracyanonickelate;
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中图分类号
学科分类号
摘要
The complex [Ni(En)2][Ni(CN)4] · 3.5H2O (I) (En = ethylenediamine) was synthesized by the reaction of [Ni(En)2](ClO4)2 and K2[Ni(CN)4] in an H-shaped tube. The crystal structure of I has been determined by single-crystal X-ray analysis. The crystal of complex I is orthorhombic, space group Pnna with a = 28.151(3), b = 8.3946(8), c = 14.5441(13)Å, M =404.76, Z = 8, V = 3437.0(5)Å3. The structure of complex I reveals infinite zigzag chains shaped structure are formed by cis-Ni(En)2-μ-(NC)2, cis-μ-(NC)2Ni(CN)2, and trans-μ-(CN)2Ni(En)2.
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页码:367 / 370
页数:3
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共 51 条
[1]  
Dunbar K.R.(1997)undefined Prog. Inorg. Chem. 45 283-undefined
[2]  
Heintz R.A.(1999)undefined Coord. Chem. Rev. 190 1023-undefined
[3]  
Verdaguer M.(2000)undefined Coord. Chem. Rev. 198 313-undefined
[4]  
Bleuzen A.(2008)undefined Inorg. Chim. Acta 361 3957-undefined
[5]  
Marcaud V.(2002)undefined Inorg. Chem. 41 6887-undefined
[6]  
Ohba M.(1997)undefined Chem. Mater. 9 1092-undefined
[7]  
Okawa H.(2001)undefined Angew. Chem. Int. Ed. 40 875-undefined
[8]  
Pinkowicz D.(2000)undefined Inorg. Chim. Acta 298 57-undefined
[9]  
Podgajny R.(2000)undefined Inorg. Chem. Commun. 3 151-undefined
[10]  
Nitek W.(2006)undefined Inorg. Chem. 45 9826-undefined