Mechanism of photoluminescence excitation of Mn2+ ions in ZnS crystals

被引:9
作者
Prokof'ev T.A. [1 ]
Polezhaev B.A. [1 ]
Kovalenko A.V. [1 ]
机构
[1] Dnepropetrovsk National University, Dnepropetrovsk, 49050
关键词
Activation energy of manganese center; Excitation spectrum; Luminescence center of manganese; Temperature dependence of photoluminescence spectra; ZnS crystals;
D O I
10.1007/s10812-006-0017-0
中图分类号
学科分类号
摘要
The mechanisms of photoluminescence excitation of Mn2+ ions in ZnS crystals have been investigated on the basis of complex analysis of the temperature dependences of the photoluminescence and photoluminescence- excitation spectra of ZnS:Mn crystals. The activation energy of a manganese luminescence center was estimated at Ea = 0.17 ± 0.05 eV. It is shown that Ea represents an energy band with a width ΔE a = 0.1 eV, within which a manganese luminescence center can experience radiationless recombination. ©2005 Springer Science+Business Media, Inc.
引用
收藏
页码:865 / 871
页数:6
相关论文
共 19 条
[1]  
Modern Crystallography [in Russian], 3, pp. 350-352, (1979)
[2]  
Tanabe Y., Sugano S., J. Phys. Soc. Jpn., 9, 5, pp. 753-766, (1954)
[3]  
Orgel L.E., J. Chem. Phys., 23, pp. 1004-1014, (1955)
[4]  
Borisenko N.D., Bulanyi M.F., Kodzhespirov F.F., Polezhaev B.A., Zh. Prikl. Spektrosk., 55, 3, pp. 452-455, (1991)
[5]  
Prokofiev T.A., Kovalenko A.V., Polezaev B.A., Bulanyi M.F., Gorban A.A., Hmelenko O.V., Semicond. Phys. Quantum Electron. & Optoelectron. (SQO), 7, 1, pp. 63-67, (2004)
[6]  
Serdyuk V.V., Vaksman Yu.F., Luminescence of Semiconductors [in Russian], (1988)
[7]  
Ilyukhina Z.P., Panasyuk E.I., Tr. FIAN, 59, pp. 38-63, (1972)
[8]  
Baranov P.G., Bulanyi M.F., Vetrov V.V., Romanov N.G., Fiz. Tverd. Tela, 26, 12, pp. 3685-3687, (1984)
[9]  
Bulanyi M.F., Polezhaev B.A., Prokof'ev T.A., Chernenko I.M., Zh. Prikl. Spektrosk., 67, pp. 208-210, (2000)
[10]  
Bulanyi M.F., Polezhaev B.A., Prokof'ev T.A., Fiz. Tekh. Poluprovodn., 32, 6, pp. 673-675, (1998)