Metal nanocluster formation in silica films prepared by rf-sputtering: an experimental study

被引:0
作者
S. Padovani
F. D'Acapito
E. Cattaruzza
A. De Lorenzi
F. Gonella
G. Mattei
C. Maurizio
P. Mazzoldi
M. Montagna
S. Ronchin
C. Tosello
M. Ferrari
机构
[1] INFM,
[2] Dipartimento di Fisica,undefined
[3] Università di Padova,undefined
[4] via Marzolo 8,undefined
[5] 35131 Padova,undefined
[6] Italy,undefined
[7] INFM,undefined
[8] European Synchrotron Radiation Facility,undefined
[9] GILDA-CRG,undefined
[10] BP 220,undefined
[11] 38043 Grenoble,undefined
[12] France,undefined
[13] INFM,undefined
[14] Dipartimento di Chimica Fisica,undefined
[15] Università di Venezia,undefined
[16] Dorsoduro 2137,undefined
[17] 30123 Venezia,undefined
[18] Italy,undefined
[19] INFM,undefined
[20] Dipartimento di Fisica,undefined
[21] Universitá di Trento,undefined
[22] 38050 Povo-Trento,undefined
[23] Italy,undefined
[24] CNR-CeFSA,undefined
[25] Centro Fisica Stati Aggregati,undefined
[26] 38050 Povo-Trento,undefined
[27] Italy,undefined
来源
The European Physical Journal B - Condensed Matter and Complex Systems | 2002年 / 25卷
关键词
PACS. Composite silica films containing metal nanoclusters were prepared by the rf- sputtering technique, in which SiO2 was co-deposited with gold+copper, gold+silver, or copper+silver. The formation of either pure or alloy clusters was studied by extended X-ray absorption fine structure spectroscopy and transmission electron microscopy. For all systems, the presence of alloy aggregates was evidenced. Moreover, small amounts of pure metal aggregates as well as dispersed or oxidized dopants were observed.;
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摘要
Composite silica films containing metal nanoclusters were prepared by the rf- sputtering technique, in which SiO2 was co-deposited with gold+copper, gold+silver, or copper+silver. The formation of either pure or alloy clusters was studied by extended X-ray absorption fine structure spectroscopy and transmission electron microscopy. For all systems, the presence of alloy aggregates was evidenced. Moreover, small amounts of pure metal aggregates as well as dispersed or oxidized dopants were observed.
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页码:11 / 17
页数:6
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