Neodymium(iii) and dysprosium(iii) naphthalene hydride complexes

被引：0
|
作者：
M. E. Burin
A. A. Logunov
V. I. Faerman
M. N. Bochkarev
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
来源：
Russian Chemical Bulletin | 2011年 / 60卷
关键词：
dysprosium; neodymium; diiodides; hydrides; naphthalenides;
D O I：
暂无
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学科分类号：
摘要：
Reactions of neodymium and dysprosium diiodide hydrides LnI2H with lithium naphthalenide in THF furnished heterobimetallic naphthalene hydride clusters (C10H8)3Ln5Li5H14 (Ln = Nd, Dy). Treatment of the latter with hexamethyldisilazane in THF leads to the removal of lithium in the form of LiN(SiMe3)2 and the formation of compounds of the composition (C10H8)3Ln5H9 (Ln = Nd, Dy). All the clusters obtained were isolated as black pyrophoric powders insoluble in THF and other organic solvents. Reactions of (C10H8)3Nd5Li5H14 and (C10H8)3Nd5H9 with cyclopentadiene lead to Cp3Nd(THF).
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页码：1591 / 1594
页数：3
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