Reduction behavior of Ru/CeO2 catalysts and their activity for wet oxidation

被引:0
作者
Seiichiro Imamura
Yo-ichi Taniguchi
Yoshio Ikeda
Saburo Hosokawa
Hiroyoshi Kanai
Hisanori Ando
机构
[1] Kyoto Institute of Technology,Department of Chemistry
[2] National Institute of Advanced Industrial Science and Technology,undefined
来源
Reaction Kinetics and Catalysis Letters | 2002年 / 76卷
关键词
Ru/CeO2; wet oxidation; acetic acid; reduction behavior;
D O I
暂无
中图分类号
学科分类号
摘要
Three kinds of Ru/CeO2 catalysts were prepared. The mobility of the oxygen on Ru and their catalytic activity in the wet oxidation of acetic acid was investigated. Ru was present in the form of RuO2, and TPR experiment showed that the reaction, RuO2 + 2H2 → Ru + 2H2O, took place in different temperature ranges depending upon the kind of the catalysts. The catalyst with easily reducible oxygen on Ru had high activity in wet oxidation, and the importance of the release of oxygen from Ru to the reactant was suggested.
引用
收藏
页码:201 / 206
页数:5
相关论文
共 50 条
[31]   Effect of the Pt oxidation state and Ce3+/Ce4+ ratio on the Pt/TiO2-CeO2 catalysts in the phenol degradation by catalytic wet air oxidation (CWAO) [J].
Lunagomez Rocha, M. A. ;
Del Angel, G. ;
Torres-Torres, G. ;
Cervantes, A. ;
Vazquez, A. ;
Arrieta, A. ;
Beltramini, J. N. .
CATALYSIS TODAY, 2015, 250 :145-154
[32]   Catalytic wet oxidation with H2O2 of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts [J].
Centi, G ;
Perathoner, S ;
Torre, T ;
Verduna, MG .
CATALYSIS TODAY, 2000, 55 (1-2) :61-69
[33]   Ce-UiO-66 Derived CeO2 Octahedron Catalysts for Efficient Ketonization of Propionic Acid [J].
Guo, Yonghua ;
Yu, Qiang ;
Fang, Huasu ;
Wang, Hua ;
Han, Jinyu ;
Ge, Qingfeng ;
Zhu, Xinli .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (39) :17269-17278
[34]   Single-Step Process To Prepare CeO2 Nanotubes with Improved Catalytic Activity [J].
Gonzalez-Rovira, Leandro ;
Sanchez-Amaya, Jose M. ;
Lopez-Haro, Miguel ;
del Rio, Eloy ;
Hungria, Ana B. ;
Midgley, Paul ;
Calvino, Jose J. ;
Bernal, Serafin ;
Botana, F. Javier .
NANO LETTERS, 2009, 9 (04) :1395-1400
[35]   Study on the structure of Fe/MgO catalysts for H2S wet oxidation [J].
Jung, KD ;
Joo, OS ;
Kim, CS .
CATALYSIS LETTERS, 2002, 84 (1-2) :52-56
[36]   Study on the Structure of Fe/MgO Catalysts for H2S Wet Oxidation [J].
Kwang-Deog Jung ;
Oh-Shim Joo ;
Chul-Sung Kim .
Catalysis Letters, 2002, 84 :53-57
[37]   Effect of calcination temperature on activity of Cu-ACF catalysts in catalytic wet oxidation of ammonia solution [J].
Hung, Chang-Mao .
ENVIRONMENTAL ENGINEERING SCIENCE, 2008, 25 (07) :951-958
[38]   Complete oxidation of acetaldehyde on Pt/CeO2-ZrO2-Bi2O3 catalysts [J].
Yasuda, K. ;
Nobu, M. ;
Masui, T. ;
Imanaka, N. .
MATERIALS RESEARCH BULLETIN, 2010, 45 (09) :1278-1282
[39]   Role of ceria-supported noble metal catalysts (Ru, Pd, Pt) in wet air oxidation of nitrogen and oxygen containing compounds [J].
J. Barbier ;
L. Oliviero ;
B. Renard ;
D. Duprez .
Topics in Catalysis, 2005, 33 :77-86
[40]   Role of ceria-supported noble metal catalysts (Ru, Pd, Pt) in wet air oxidation of nitrogen and oxygen containing compounds [J].
Barbier-Jr, J ;
Oliviero, L ;
Renard, B ;
Duprez, D .
TOPICS IN CATALYSIS, 2005, 33 (1-4) :77-86