Synthesis, Crystal Structure, and Properties of a 3D Cu(I) Coordination Polymer Based on Cu3(CN)2 Clusters and 1,3-Di-(1,2,4-Triazole-4-yl)Benzene

被引：0
作者：
Shao-Bin Miao
Zhao-Hao Li
Bao-Ming Ji
Dong-Sheng Deng
Chun-Ying Xu
Le Zhou
机构：
[1] Northwest A&F University,College of Science
[2] Luoyang Normal University,College of Chemistry and Chemical Engineering
来源：
Journal of Cluster Science | 2014年 / 25卷
关键词：
1,3-Di-(1,2,4-triazole-4-yl)benzene; Coordination polymer; Synthesis; Crystal structure; Cluster;
D O I：
暂无
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学科分类号：
摘要：
A new coordination polymer, [Cu3(dtb)(CN)3]n (1) (dtb = 1,3-di-(1,2,4-triazole-4-yl)benzene) based on Cu3(CN)2 clusters, has been synthesized under solvothermal conditions, and characterized by elemental analysis, infrared spectrometry, powder X-ray diffraction, thermogravimetric analysis, and single-crystal X-ray diffraction. Complex 1 exhibits a three-dimensional twofold interpenetrated net with 6-connected uninodal topology. Moreover, solid state luminescent property of 1 has been investigated at room temperature.
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页码：1137 / 1145
页数：8
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