A palladacyclic azobenzene derivative as a catalyst for carbon-carbon bond formation reactions

被引：0
|
作者：
L. A. Bulygina
N. S. Khrushcheva
S. M. Peregudova
V. I. Sokolov
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2012年 / 61卷
关键词：
azobenzene; palladacycles; catalysis; the Heck reaction; the Suzuki reaction; voltammetry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A bis-chelated palladacycle in which the Pd atom is [(C, N)(C, N)]-tetracoordinated to two azobenzene ligands proved to be a moderately active catalyst for the Suzuki and Heck reactions. A voltammetric study revealed that the two-electron oxidation of this complex is accounted for by the irreversible PdII/PdIV transition.
引用
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页码：1998 / 2000
页数：2
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