Effect of the solvent on the hydrolysis of the iron nitrosyl complex {Fe2[S(CH2)2NH3]2(NO)4}SO4·2.5H2O: spectroscopic and kinetic investigations of its monomer and dimer forms

被引：0
作者：
L. A. Syrtsova
N. A. Sanina
B. L. Psikha
A. V. Kulikov
A. V. Chernyak
N. I. Shkondina
T. N. Rudneva
O. V. Shaposhnikova
A. I. Kotel’nikov
S. M. Aldoshin
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 2011年 / 60卷
关键词：
iron nitrosyl complexes; nitrogen monoxide donors; ESR spectroscopy; H NMR spectroscopy; kinetic measurements;
D O I：
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学科分类号：
摘要：
The hydrolysis of the iron nitrosyl complex {Fe2[S(CH2)2NH3]2(NO)4}SO4·2.5H2O (CysAm) in water is not accompanied by the formation of its monomer form and is a reversible process. According to the ESR, 1H NMR, and spectrophotometric data, the dissolution of CysAm in DMSO affords the monomer form of CysAm. The kinetic parameters of the hydrolysis of CysAm in the dimer and monomer forms were determined by kinetic modeling.
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页码：1144 / 1149
页数：5
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