Breaking free of chiral symmetry

被引：0
|
作者：
Eiji Yashima
机构：
[1] Graduate School of Engineering,Eiji Yashima is in the Department of Molecular Design and Engineering
[2] Nagoya University,undefined
[3] Chikusa-ku,undefined
[4] Nagoya 464-8603,undefined
[5] Japan. yashima@apchem.nagoya-u.ac.jp,undefined
来源：
Nature Chemistry | 2011年 / 3卷
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摘要：
Helical macromolecules are ubiquitous in nature, and almost always adopt a one-handed conformation. Synthetic systems, in contrast, are typically obtained in racemic right- and left-handed mixtures. A helical phenylene oligomer has now been prepared that forms a non-racemic mixture on crystallization, and on oxidation locks one conformation in.
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页码：12 / 14
页数：2
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