Effect of Al and Ce on Zr-pillared bentonite and their performance in catalytic oxidation of phenol

被引：0
作者：
Saida Mnasri-Ghnimi
Najoua Frini-Srasra
机构：
[1] Centre National des Recherches en Sciences des Matériaux,Laboratoire de Physico
[2] Technopole Borj Cédria,chimie des Matériaux Minéraux et leurs Applications
[3] Faculté des Sciences de Tunis,Départements de Chimie
来源：
Russian Journal of Physical Chemistry A | 2016年 / 90卷
关键词：
pillared clays; heterogeneous catalysis; catalytic oxidation in water; phenol; hydrogen peroxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Catalysts based on pillared clays with Zr and/or Al and Ce–Zr and/or Al polycations have been synthesized from a Tunisian bentonite and tested in catalytic oxidation of phenol at 298 K. The Zr-pillared clay showed higher activity than the Al-one in phenol oxidation. Mixed Zr–Al pillars lead to an enhancement of the catalytic activity due to the modification of the zirconium properties. The clays modified with Ce showed high conversions of phenol and TOC thus showing to be very selective towards the formation of CO2 and H2O.
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页码：1766 / 1773
页数：7
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