Polymers based on anionic octahedral cluster chalcocyanohydroxorhenium complexes and cations [Cu(En)2]2+

被引:0
|
作者
A. V. Ermolaev
A. I. Smolentsev
Yu. V. Mironov
机构
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk State University,undefined
来源
Russian Journal of Coordination Chemistry | 2014年 / 40卷
关键词
Ethylenediamine; Coordination Chemistry; Coordination Polymer; Cluster Anion; Polymer Compound;
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中图分类号
学科分类号
摘要
Polymer compounds [Cu(En)2(H2O)2][{Cu(En)2}Re6S8(CN)4(OH)2] · 5.5H2O (I) and [Cu(En)2(H2O)2][{Cu(En)2}Re6Se8(CN)4(OH)2] · 5H2O (II) are synthesized by the layering of an ammonia solution of CuCl2 with ethylenediamine (En) on aqueous solutions of the corresponding octahedral cluster chalcocyanohydroxorhenium complexes. The compounds are characterized by IR spectroscopy and elemental and X-ray diffraction analyses.
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页码:558 / 564
页数:6
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