Study of the Ligand Substitution Reaction [Fe(CN)5(4-tbupy)]3- + Pyrazine in Concentrated Aqueous Electrolyte Solutions: Estimation of the Activation Volume

被引：0
作者：
Gaspar Fernández
María del Mar Graciani
Amalia Rodríguez
María Múñoz
María Luisa Moyá
机构：
[1] Universidad de Sevilla,Departamento de Química Física
来源：
Reaction Kinetics and Catalysis Letters | 2000年 / 70卷
关键词：
Fe(CN); (4-; bupy); kinetics; electrolytes; substitution;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The ligand substitution reaction [Fe(CN)5(4-tbupy)]3- + pyrazine (4-tbupy=4-tertbutylpyridine) was studied in aqueous concentrated electrolyte solutions at 298 K. Plots of ln(k/kw) against (γ-γw), where the subscript w refers to pure water and γ is the surface tension of the appropriate salt solution, gave a common straight line for all the electrolytes studied and permits to estimate the activation volume.
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页码：389 / 394
页数：5
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