Catalytic Activation of Methane Using n-Pentane as Co-reactant over Zn/H-ZSM-11 Zeolite

被引：0
作者：
Oscar A. Anunziata
Griselda V. González Mercado
Liliana B. Pierella
机构：
[1] Universidad Tecnologica Nacional,Grupo Fisicoquímica de Nuevos Materiales, Centro de Investigacion y Tecnología Química (CITeQ), Facultad Cordoba
来源：
Catalysis Letters | 2003年 / 87卷
关键词：
methane conversion; co-reactant; -pentane; higher hydrocarbons; Zn zeolites;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The catalytic conversion of methane (C1) into higher hydrocarbons using n-pentane (n-C5) as co-reactant over Zn/H-ZSM-11 zeolite material was studied. The aromatics yield was very high, achieving values of over 40 mol% at 500 °C and w/f = 30 g h mol-1 with a C1/(C1+C5) molar fraction (XC1) = 0.30. Contact time and time-on-stream effects on the product distribution were analyzed in detail in order to obtain information about the evolution of different species. The C1 conversion was as high as 30 mol% without COx reaction products.
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页码：167 / 171
页数：4
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