Electrochemical synthesis, cathodoluminescence, and optical absorption of CdS and Cd1–хZnхS (0 < x ≤ 0.017) films

被引:0
作者
E. A. Senokosov
I. N. Odin
M. V. Chukichev
V. M. Ishimov
I. V. Demidenko
R. R. Rezvanov
机构
[1] Shevchenko State University,
[2] Moscow State University,undefined
[3] National Nuclear Research University MEPhI (Moscow Engineering Physics Institute),undefined
来源
Inorganic Materials | 2016年 / 52卷
关键词
electrochemical synthesis; films; lattice parameters; optical absorption; cathodoluminescence; band gap;
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摘要
Using electrochemical deposition from an aqueous solution of Na2S2O3 and CdSO4, with a cadmium anode, we have grown CdS films on tin dioxide substrates (cathode). The CdS films have been shown to be polycrystalline, with the wurtzite structure. From the optical absorption and cathodoluminescence spectra of the films, we have determined their band gap at 298 and 78 K. With a zinc anode, we obtained polycrystalline Cd1–хZnхS (0 < x ≤ 0.017) films with the wurtzite structure. The Cd0.983Zn0.017S films have a larger band gap and higher luminescence intensity than do the CdS films.
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页码:1103 / 1107
页数:4
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