Influence of the size of aromatic chelate ligands on the one-dimensional chains of copper(II) dicarboxylate coordination polymers

被引：0
作者：
Y. J. Song
P. Zhang
J. W. Ji
Z. B. Han
机构：
[1] Liaoning University,College of Chemistry
来源：
Russian Journal of Coordination Chemistry | 2009年 / 35卷
关键词：
Coordination Chemistry; Coordination Polymer; Dicarboxylate; Phenazine; Coordination Water Molecule;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
To investigate the influence of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers, two one-dimensional coordination compounds [Cu(BDC)(TATP)(H2O)]n (I) and [Cu(BDC)(DPPZ)]n (II), (BDC = 1.4-benzenedicarboxylate, TATP = 1,4,8,9-tetranitrogentrisphene, DPPZ = dipyrido[3,2-a:2′,3′-c]phenazine) were synthesized under similar conditions and structurally characterized by X-ray crystallography. Compounds I and II have the similar zigzag chain structure, but the substitution of TATP with DPPZ results in the difference of the degree of bending of the chain, indicating that the sizes of the rigid aromatic chelate ligands have important effect on the structures of their complexes.
引用
收藏
页码：698 / 703
页数：5
相关论文
共 62 条
  • [1] Ockwig N.W.(2005)undefined Acc. Chem. Res. 38 176-undefined
  • [2] Friedrichs O.D.(2005)undefined Acc. Chem. Res. 38 273-undefined
  • [3] O’Keeffe M.(2004)undefined Angew. Chem. Int. Ed. 34 1466-undefined
  • [4] Yaghi O.M.(2004)undefined J. Am. Chem. Soc. 126 1308-undefined
  • [5] Bradshaw D.(2002)undefined Dalton Trans. 2 2714-undefined
  • [6] Claridge J.B.(2007)undefined Chem. Commun. 40 4107-undefined
  • [7] Cussen E.J.(2002)undefined Chem. Eur. J. 8 2027-undefined
  • [8] Rao C.N.R.(1995)undefined Angew. Chem. Int. Ed. 34 2127-undefined
  • [9] Natarajan S.(1998)undefined Inorg. Chem. 37 2645-undefined
  • [10] Vaidhyanathan R.(2002)undefined Angew. Chem. Int. Ed. 41 3371-undefined
1234567