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- [1] Stereochemistry of ketone olefination with methyl trimethylsilylacetateRUSSIAN CHEMICAL BULLETIN, 2005, 54 (04) : 1046 - 1047Grigorieva, NY
Stereochemistry of ketone olefination with methyl trimethylsilylacetate
被引：0
|作者：
N. Ya. Grigorieva
机构：
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
来源：
Russian Chemical Bulletin
|
2005年
/
54卷
关键词：
(;
)-stereoselective olefination of ketones;
sulfides;
methyl 7-methyl-3-propyl-4-(phenylthio)deca-2(;
),6(;
)- and 7-methyl-3-propyl-4-(phenylthio)deca-2(;
),6(;
)-dienoates;
8-methyl-5-(phenylthio)undec-7(;
)-en-4-ol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
High (Z)-stereoselectivity of olefination of methyl α-phenylthioalkyl and methyl α-phenylthioalkenyl ketones with methyl trimethylsilylacetate decreases in the case of ketones containing a higher alkyl-substituent in place of the methyl group.
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页码：1046 / 1047
页数：1
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