Measurement and correlation of solubility of xylitol in binary water+ethanol solvent mixtures between 278.00 K and 323.00K

被引:0
作者
Zhanzhong Wang
Qian Wang
Xiangshan Liu
Wenzhi Fang
Yan Li
Huazhi Xiao
机构
[1] Tianjin University,School of Chemical Engineering and Technology
来源
Korean Journal of Chemical Engineering | 2013年 / 30卷
关键词
Xylitol; Solubility; Measurement; Correlation; Thermodynamic Properties;
D O I
暂无
中图分类号
学科分类号
摘要
The solubility of xylitol in ethanol+water solvent mixtures was measured at temperatures ranging from 278.00 K to 323.00 K at atmospheric pressure by using a laser technique. The results of these measurements were correlated by the combined nearly ideal binary solvent CNIBS/Redlich-Kister equation. The experimental solubility and correlation equation in this work can be used as essential data and models in the purification process of xylitol. The variant 2 in the CNIBS/R-K models was confirmed to be more adaptable to predict solubility of xylitol in binary ethanol +water system. Using the experimentally measured solubilities, the thermodynamic properties of dissolution of xylitol, such as Gibbs energy, molar enthalpy of dissolution, and molar entropy of dissolution, were calculated.
引用
收藏
页码:931 / 936
页数:5
相关论文
共 64 条
  • [1] Rivas B.(2006)undefined J. Agric. Food Chem. 54 4430-undefined
  • [2] Torre P.(2002)undefined J. Chem. Eng. 90 291-undefined
  • [3] Dominguez J. M.(2010)undefined Green Chem. 12 1648-undefined
  • [4] Converti A.(2004)undefined J. Chem. Eng. Data 49 1671-undefined
  • [5] Parajo J. C.(2005)undefined Chin. Opt. Lett. 3 149-undefined
  • [6] Faveri D. D.(2005)undefined Ind. Eng. Chem. Res. 44 3783-undefined
  • [7] Perego P.(2004)undefined J. Chem. Eng. Data 49 697-undefined
  • [8] Converti A.(2001)undefined J. Chem. Eng. Data 46 234-undefined
  • [9] Borghi D.M.(1992)undefined J. Thermochim. Acta 198 71-undefined
  • [10] Payne S.M.(1991)undefined Phys. Chem. Liq. 23 27-undefined