trans-dinitro- and trans-dinitratoruthenium complexes [RuNO(NH3)2(NO2)2(OH)] and [RuNO(NH3)2(H2O)(NO3)2]NO3·H2O

被引：0
作者：
M. A. Il’in
E. V. Kabin
V. A. Emel’yanov
I. A. Baidina
V. A. Vorob’yov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2009年 / 50卷
关键词：
ruthenium; nitroso complexes; ammino complexes; nitro complexes; nitrato complexes; spent nuclear fuel; X-ray analysis;
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摘要：
Methods for the synthesis of trans-diammino complexes [RuNO(NH3)2(NO2)2(OH)] (I) and [RuNO(NH3)2(H2O)(NO3)2](NO3)·H2O (II) are suggested. The compounds were studied by IR spectroscopy and X-ray phase and X-ray structural analyses. Crystal data: space group P-1; a = 6.2328(2) Å, b = 11.0488(3) Å, c = 11.0981(4) Å, α = 71.942(1)°, β = 83.291(1)°, γ = 86.877(1)° (I); space group P21; a = 6.6290(2) Å, b = 13.4389(5) Å, c = 7.0180(2) Å, β 114.281(1)° (II). Complex II readily lost some part of crystal water on storage in open air.
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页码：328 / 334
页数：6
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