Formation and Thermodynamics of Mg-Al-Ti-O Complex Inclusions in Mg-Al-Ti-Deoxidized Steel

被引:0
作者
Ying Ren
Lifeng Zhang
Wen Yang
Haojian Duan
机构
[1] University of Science and Technology Beijing (USTB),Beijing Key Laboratory of Green Recycling and Extraction of Metals (GREM) and the School of Metallurgical and Ecological Engineering
来源
Metallurgical and Materials Transactions B | 2014年 / 45卷
关键词
Complex Inclusion; MgAl2O4; Molten Steel; Submerged Entry Nozzle; Liquid Inclusion;
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摘要
The formation of Mg-Al-Ti-O complex inclusions in steel was investigated by laboratory experiments and thermodynamic calculation. The composition evolutions of Mg-Al-Ti-O inclusions in steel with different contents of [Al], [Mg], and [Ti] were discussed. Mg-Al-Ti-O complex inclusion with high TiOx content was liquid at 1873 K (1600 °C), indicating MgAl2O4 spinel inclusions can be modified to low melting temperature ones by combining TiOx component. The stability diagram of Al-Mg-Ti-O system inclusions in the molten steel at 1873 K (1600 °C) was calculated, considering many kinds of oxide inclusions such as MgO, Al2O3, TiOx, MgTi2O4, MgAl2O4, Al2TiO5, and liquid inclusion. The thermodynamic calculations are in good agreement with experimental results, which can predict the formation of Al-Mg-Ti-O complex inclusions in molten steel with a large concentration range of [Al], [Mg], and [Ti].
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页码:2057 / 2071
页数:14
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