Synthesis, crystal structure and spectroscopic properties of a copper(II) complex of the Schiff-base derived from picolinaldehyde N-oxide and 4-aminoantipyridine

被引：0
|
作者：
Liang H. [1 ]
Yu Q. [1 ]
Hu R.-X. [1 ]
Zhou Z.-Y. [2 ]
Zhou X.-G. [2 ]
机构：
[1] Department of Chemistry, Guangxi Normal University, Guilin
[2] Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu
来源：
Transition Metal Chemistry | 2002年 / 27卷 / 4期
关键词：
Copper; Physical Chemistry; Crystal Structure; Inorganic Chemistry; EtOH;
D O I：
10.1023/A:1015096107672
中图分类号：
学科分类号：
摘要：
Synthesis, crystal structure and spectroscopic properties of a copper(II) complex of the Sciff-base (PNOAAP) derived from picolinaldehyde N-oxide and 4-aminoantipyridine were presented. Owing to conjunction interaction of the imino double bond, one plane was formed between the pyrazoline ring and the pyridine ring. It is found that the δ values corresponding to identical protons in the PNOAAP ligand shift upfield and also shows splitting due to structural isomerization and the formation of complex. © 2002 Kluwer Academic Publishers.
引用
收藏
页码：454 / 457
页数：3
相关论文
共 50 条
  • [1] Synthesis and Crystal Structure of a Zinc(II) Complex Salt with the Schiff Base of Picolinaldehyde N-oxide and Semicarbazone
    YU Qing ZHU Li-Gang BIAN He-Dong DENG Ji-Hua YANG Xiao-E GUO Gui-Quan LIANG Hong② (College of Chemistry and Chemical Engineering
    Chinese Journal of Structural Chemistry, 2005, (11) : 53 - 57+8
  • [2] Synthesis and crystal structure of a zinc(II) complex salt with the Schiff base of picolinaldehyde N-oxide and semicarbazone
    Yu, Q
    Zhu, LG
    Bian, HD
    Deng, JH
    Yang, XE
    Guo, GQ
    Liang, H
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (11) : 1271 - 1275
  • [3] Synthesis, crystal structure of Schiff base 6-methyl-2-picolinaldehyde Thiosemicarbazone N-oxide
    Hu, RX
    Yu, Q
    Liang, H
    Zhou, ZY
    Zhou, XG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (04) : 286 - 290
  • [4] Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystal structure, and magnetic study
    Adhikary, Chandan
    Sen, Rupam
    Bocelli, Gabriele
    Cantoni, Andrea
    Solzi, Massimo
    Chaudhuri, Siddhartha
    Koner, Subratanath
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (22) : 3573 - 3582
  • [5] Synthesis and crystal structure of copper(II) compound with didentate Schiff-base ligand
    Li, L
    Ding, B
    Chen, P
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (01) : 25 - 28
  • [6] Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand
    Xue, ZM
    Zhang, XJ
    Tian, YP
    Wu, JY
    Jiang, MH
    Fun, HK
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (03) : 265 - 269
  • [7] An Unprecedented Dodecanuclear Copper(II) Complex Derived from an Unsymmetrical Schiff-Base Ligand
    Bhunia, Pradip
    Mayans, Julia
    Escuer, Albert
    Ghosh, Ashutosh
    CHEMISTRYSELECT, 2022, 7 (15):
  • [8] Synthesis, crystal structure and biocidal study of a new Schiff-base Zn(II) complex derived from asymmetrical tripodal tetraamine
    Gao, J
    Chen, J
    Xu, XY
    Li, SA
    Yang, XJ
    Lu, LD
    Wang, X
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (11) : 1320 - 1324
  • [9] Synthesis, crystal structure and nuclease activity of a Schiff base copper(II) complex
    Li, LZ
    Zhao, C
    Xu, T
    Ji, HW
    Yu, YH
    Guo, GQ
    Chao, H
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (05) : 1076 - 1082
  • [10] Synthesis, crystal structure and characterization of a new mononuclear Zn(II) complex from Schiff-base ligand
    Jun, Chen
    Xu Xing-You
    Jian, Gao
    Li Yan-Hui
    Xu Guo-Xiang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (06) : 632 - 636
12345