Nickel(II) and Iron(II) coordination compounds with octahydrotriborate(1–) anion [ML3]{B3H8}2 (M = Fe2+, Ni2+; L = bipy, phen)

被引:0
作者
N. A. Selivanov
A. Yu. Bykov
M. S. Grigor’ev
K. Yu. Zhizhin
N. T. Kuznetsov
机构
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry
来源
Doklady Chemistry | 2016年 / 467卷
关键词
Phen; Bipy; Coordination Compound; Phenanthroline; DOKLADY Chemistry;
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摘要
Methods of synthesis have been developed for new types of promising precursors of metal borides, coordination compounds [ML3]B{3H8{2 (M = Fe2+, Ni2+; L = bipy, phen), using modified procedures of synthesis of octahydrotriborate anion. Compounds [Ni(bipy)3]B{3H8}2, [Ni (phen)3]B{3H8}2 and [Fe(phen)3]B{3H8}2 were prepared and characterized by single-crystal X-ray diffraction.
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页码:64 / 68
页数:4
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