La0.75Sr0.25Cr0.5Mn0.5O3−δ-Ce0.8Gd0.2O1.9 composite electrodes as anodes in LaGaO3-based direct carbon solid oxide fuel cellsLa0.75Sr0.25Cr0.5Mn0.5O3−δ–Ce0.8Gd0.2O1.9复合电极用作LaGaO3基直接碳固体氧化物燃料电池阳极的研究

被引:0
作者
Tian-yu Chen
Yong-min Xie
Zhi-bin Lu
Liang Wang
Zhe-qin Chen
Xiao-cong Zhong
Jia-ming Liu
Rui-xiang Wang
Zhi-feng Xu
Shao-bo Ouyang
机构
[1] Jiangxi University of Science and Technology,Faculty of Materials Metallurgy and Chemistry
[2] Ganzhou Engineering Technology Research Center of Green Metallurgy and Process Intensification,undefined
[3] Jiangxi College of Applied Technology,undefined
来源
Journal of Central South University | 2022年 / 29卷
关键词
direct carbon solid oxide fuel cells; anode material; La; Sr; Cr; Mn; O; -Ce; Gd; O; composite electrodes; Ni nanoparticles; 直接碳固体氧化物燃料电池; 阳极材料; La; Sr; Cr; Mn; O; −Ce0.8Gd0.2O1.9复合电极; Ni 纳米颗粒;
D O I
暂无
中图分类号
学科分类号
摘要
Direct carbon solid oxide fuel cells (DC-SOFCs) are promising, green, and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures. Developing suitable anode materials for DC-SOFCs is a substantial scientific challenge. Herein we investigated the use of La0.75Sr0.25Cr0.5Mn0.5O3−δ-Ce0.8Gd0.2O1.9 (LSCM—GDC) composite electrodes as anodes for La0.9Sr0.1Ga0.8Mg0.2O3−δ electrolyte-based DC-SOFCs, with Camellia oleifera shell char as the carbon fuel The LSCM—GDC-anode DC-SOFC delivered a maximum power density of 221 mW/cm2 at 800 °C and it significantly improved to 425 mW/cm2 after Ni nanoparticles were introduced into the LSCM—GDC anode through wet impregnation The microstructures of the prepared anodes were characterized, and the stability of the anode in a DC-SOFC and the influence of catalytic activity on open circuit voltage were studied The above results indicate that LSCM—GDC anode is promising to be applied in DC-SOFCs.
引用
收藏
页码:1788 / 1798
页数:10
相关论文
共 156 条
  • [21] Rong B-G(2014)Use of ash-free “Hyper-coal” as a fuel for a direct carbon fuel cell with solid oxide electrolyte [J] International Journal of Hydrogen Energy 39 12386-9194
  • [22] Nakagawa N(2011)Direct carbon solid oxide fuel cell—A potential high performance battery [J] International Journal of Hydrogen Energy 36 9189-1620
  • [23] Ishida M(2017)A high performance direct carbon solid oxide fuel cell stack for portable applications [J] Acta Physico-Chimica Sinica 33 1614-8
  • [24] Tang Y-B(2021)Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack [J] Energy 227 120456-420
  • [25] Liu J(2015)Electrochemical gas-electricity cogeneration through direct carbon solid oxide fuel cells [J] Journal of Power Sources 277 1-29330
  • [26] Zhang L(2020)Efficient use of waste carton for power generation, tar and fertilizer through direct carbon solid oxide fuel cell [J] Renewable Energy 158 410-1161
  • [27] Xiao J(2020)Highperformance gas-electricity cogeneration using a direct carbon solid oxide fuel cell fueled by biochar derived from camellia oleifera shells [J] International Journal of Hydrogen Energy 45 29322-893
  • [28] Xie Y-M(2020)Solid oxide fuel cells in combination with biomass gasification for electric power generation [J] Chinese Journal of Chemical Engineering 28 1156-21176
  • [29] Xie Y-M(2015)A facile method of preparing Fe-loaded activated carbon fuel for direct carbon solid oxide fuel cells [J] Fuel 159 887-1268
  • [30] Tang Y-B(2017)A high performance direct carbon solid oxide fuel cell fueled by Ca-loaded activated carbon [J] International Journal of Hydrogen Energy 42 21167-208