Ion-Exchange Ability of Polyaniline-Polyvinyl Alcohol Colloids with Various Anions

被引:0
作者
Hidenobu Nakao
Tsutomu Nagaoka
Kotaro Ogura
机构
[1] Yamaguchi University,Department of Applied Chemistry, Faculty of Engineering
来源
Analytical Sciences | 1997年 / 13卷
关键词
Conducting polymer; polymer colloid; soluble polymer; ion exchange;
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摘要
Polyaniline-polyvinyl alcohol (PAPVA) colloids consisting of polyaniline (PA) and polyvinyl alcohol (PVA) were prepared. This colloid is electrochemically active and can adsorb various anions. The adsorption occurs electro-chemically or chemically. The selectivity sequence of the PAPVA colloid toward monovalent anions was SCN-> ClO4−>BF4−>Br− ≫ Cl−≈CF3COO−≫C6H5SO3−. Adsorption ability of the PAPVA colloid toward each anion was enhanced when large anions such as G6H5SO3−, were doped into the colloid.
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页码:327 / 331
页数:4
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