Assignment of the absolute configuration of fischerin by computed nmr chemical shifts

被引：0
作者：
S. K. Amini
机构：
[1] Chemistry and Chemical Engineering Research Center of Iran,
来源：
Journal of Structural Chemistry | 2015年 / 56卷
关键词：
configuration; NMR; computational; fischerin;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The unassigned configurations of a toxic metabolite to mammals extracted from Neosartorya fischeri (fischerin) in C19, C20, C21, and C22 are assigned as R, R, R, and S, respectively. In this assignment, the extensive ab initio calculations followed by chemical shift computations are performed. Computed chemical shifts are correlated to experimental ones in order to find the correct configuration shown here.
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页码：1334 / 1341
页数：7
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