Synthesis and Structure of N,N-Dimethyldithiocarbamates of Tetraphenylantimony and Tetra-p-tolylantimony

被引：0
作者：
V. V. Sharutin
O. K. Sharutina
T. P. Platonova
A. P. Pakusina
A. V. Gerasimenko
E. A. Gerasimenko
B. V. Bukvetskii
D. Yu. Popov
机构：
[1] Blagoveshchensk State Pedagogical University,Institute of Chemistry, Far East Division
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2003年 / 29卷
关键词：
Sodium; Chloride; Physical Chemistry; Bond Length; Diffraction Data;
D O I：
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摘要：
Tetraphenylantimony N,N-dimethyldithiocarbamate (I) and tetra-p-tolylantimony N,N-dimethyldithiocarbamate (II) were synthesized via the reaction of tetraarylantimony chloride Ar4SbCl (Ar = C6H5 or C6H4Me-4) with sodium N,N-dimethyldithiocarbamate in water. According to the X-ray diffraction data, the tetraarylantimony N,N-dimethyldithiocarbamate molecules have a distorted octahedral configuration. The Sb–S bond lengths are equal to 2.7158(5) Å, 2.7440(5) Å and 2.761(2) Å, 2.8002(2) Å for I and II, respectively.
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页码：11 / 15
页数：4
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