On the Prins reaction of terminal olefins and formaldehyde in trifluoroacetic acid

被引：0
作者：
Hasanain A. A. Almohseni
Matthew A. H. Stent
David M. Hodgson
机构：
[1] University of Oxford,Department of Chemistry
[2] Chemistry Research Laboratory,undefined
来源：
Chemistry of Heterocyclic Compounds | 2018年 / 54卷
关键词：
formaldehyde; terminal alkenes; tetrahydropyrans; trifluoroacetic acid; Prins reaction;
D O I：
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学科分类号：
摘要：
The Prins reaction of 1-heptene, as a representative terminal alkene, with formaldehyde in trifluoroacetic acid produces 3-butyl-4-(trifluoroacetoxy)tetrahydropyran and/or 3-butyl-4-hydroxytetrahydropyran; it does not provide (as previously reported by Talipov and coworkers) a route to 3-alkyl-2,5-dihydrofurans and 4-alkyl-3-hydroxytetrahydrofurans.
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页码：474 / 477
页数：3
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