TiCl4-Et2AlCl-Catalyzed cycloaddition of 1,2-dienes to 1,3,5-cycloheptatriene

被引：12
|
作者：
D'yakonov, V. A. [1 ]
Kadikova, G. N. [1 ]
Khalilov, L. M. [1 ]
Dzhemilev, U. M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
cycloheptatriene; metal complex catalysis; 1,2-dienes; bicyclo[4.2.1]nonanes; allenes; cycloaddition; REARRANGEMENT PATHWAYS; RING-SYSTEM; CYCLOHEPTATRIENE; ALLENES;
D O I：
10.1007/s11172-011-0077-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A reaction of 1,3,5-cycloheptatriene with 1,2-dienes in the presence of the two-component catalytic system TiCl4-Et2AlCl leads to regio- (similar to 99%) and stereoselective (> 85%) formation of substituted endo-bicyclo[4.2.1]nona-2,4-dienes in up to 80% yields.
引用
收藏
页码：499 / 502
页数：4
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