Chromium(III), manganese(II), iron(III), cobalt(II), nickel(II) and copper(II) complexes with a pentadentate, 15-membered new macrocyclic ligand

被引：0

作者：

Sulekh Chandra

Karuna Gupta

机构：

[1] University of Delhi,Department of Chemistry, Zakir Husain College

来源：

Transition Metal Chemistry | 2002年 / 27卷

关键词：

Nickel; Chromium; Cobalt; Manganese; Ethane;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Complexes of CrIII, MnII, FeIII, CoII, NiII and CuII containing a macrocyclic pentadentate nitrogen–sulphur donor ligand have been prepared via reaction of a pentadentate ligand (N3S2) with transition metal ions. The N3S2 ligand was prepared by [1 + 1] condensation of 2,6-diacetylpyridine with 1,2-di(o-aminophenylthio(ethane. The structures of the complexes have been elucidated by elemental analyses, molar conductance, magnetic susceptibility measurements, i.r., electronic and e.p.r. spectral studies. The complexes are of the high spin type and are six-coordinate.

引用

页码：196 / 199

页数：3

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