Chromium(III), manganese(II), iron(III), cobalt(II), nickel(II) and copper(II) complexes with a pentadentate, 15-membered new macrocyclic ligand

被引：0
作者：
Sulekh Chandra
Karuna Gupta
机构：
[1] University of Delhi,Department of Chemistry, Zakir Husain College
来源：
Transition Metal Chemistry | 2002年 / 27卷
关键词：
Nickel; Chromium; Cobalt; Manganese; Ethane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Complexes of CrIII, MnII, FeIII, CoII, NiII and CuII containing a macrocyclic pentadentate nitrogen–sulphur donor ligand have been prepared via reaction of a pentadentate ligand (N3S2) with transition metal ions. The N3S2 ligand was prepared by [1 + 1] condensation of 2,6-diacetylpyridine with 1,2-di(o-aminophenylthio(ethane. The structures of the complexes have been elucidated by elemental analyses, molar conductance, magnetic susceptibility measurements, i.r., electronic and e.p.r. spectral studies. The complexes are of the high spin type and are six-coordinate.
引用
收藏
页码：196 / 199
页数：3
相关论文
共 57 条
[1]  
Fenton D.E.(1982)undefined Inorg. Chim. Acta 62 57-undefined
[2]  
Casellato U.(1992)undefined Acta Chem. Scand. 46 1025-undefined
[3]  
Vigato P.A.(1979)undefined Chem. Soc. Rev. 8 199-undefined
[4]  
Vidali M.(1976)undefined Isr. J. Chem. 15 277-undefined
[5]  
Guerriero P.(1984)undefined J. Am. Chem. Soc. 106 2328-undefined
[6]  
Vigato P.A.(1991)undefined J. Am. Chem. Soc. 113 2965-undefined
[7]  
Fenton D.E.(1993)undefined Inorg. Chem. 32 854-undefined
[8]  
Hellier P.C.(1993)undefined Pure Appl. Chem. 65 473-undefined
[9]  
Casellato U.(1993)undefined Inorg. Chem. 32 1396-undefined
[10]  
Vigato P.A.(1970)undefined J. Am. Chem. Soc. 92 1924-undefined
123456