Effect of the monomer concentration on piperylene cationic polymerization in the presence of the TiCl4-trichloroacetic acid catalytic system

被引:0
作者
V. A. Rozentsvet
V. G. Kozlov
机构
[1] Russian Academy of Sciences,Volga Basin Ecology Institute
来源
Russian Chemical Bulletin | 2007年 / 56卷
关键词
piperylene; cationic polymerization; kinetics; molecular parameters; branching;
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摘要
The effect of the monomer concentration on the kinetics of cationic polymerization of piperylene in the presence of the TiCl4-trichloroacetic acid catalytic system and molecular weight of the produced polymer was studied. At high monomer concentrations, the high-molecular-weight peak related to the formation of the branched fraction appears in the molecular weight distribution curve of the produced polymer.
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页码:1359 / 1362
页数:3
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