Production of high-octane gasoline from straight-run gasoline on ZSM-5 modified zeolites

被引:0
作者
V. I. Erofeev
I. S. Khomyakov
L. A. Egorova
机构
[1] National Research Tomsk Polytechnic University,
[2] National Research Tomsk State University,undefined
来源
Theoretical Foundations of Chemical Engineering | 2014年 / 48卷
关键词
Zeolite; Temperature Program Desorption; Zeolite Catalyst; Octane Number; Heteropoly Compound;
D O I
暂无
中图分类号
学科分类号
摘要
The acid and catalytic properties of ZSM-5 zeolites modified with tungsten heteropolycompounds were studied in the process of production of high-octane gasoline from straight-run gasoline. It was shown that introducing cobalt tungsten-bismuthate, cobalt tungsten-phosphate, and iron tungsten-phosphate heteropolycompounds in zeolite in amount of 1–3 wt % makes it possible to increase the yield of high-octane gasoline by 5–10% and that of alkyl aromatic hydrocarbons by 5–7% from straight-run gasoline compared to initial H-ZKE-G zeolite. The interrelation between acid and catalytic properties of zeolite catalysts modified with cobalt tungsten-bismuthate, cobalt tungsten-phosphate, and iron tungsten-phosphate heteropolycompounds was established for the process of producing high-octane gasoline from straight-run gasoline.
引用
收藏
页码:71 / 76
页数:5
相关论文
共 22 条
[1]  
Korobitsyna LL(1997)Physicochemical and catalytic properties of iron-containing zeolites Russ. J. Phys. Chem. A 71 54-undefined
[2]  
Velichkina LM(2001)Pyrolysis of straight-run naphtha on ZSM-5 zeolites, modified with alkali-earth metal cations Russ. J. Appl. Chem. 74 235-undefined
[3]  
Antonova NV(2001)Effect of high-temperature treatment of pentasils on their acid and catalytic properties in conversion of straight-run naphthas Russ. J. Appl. Chem. 74 1846-undefined
[4]  
Vosmerikov AV(2003)Transformations of straight-run naphthas on indium-modified pentasils Russ. J. Appl. Chem. 76 1083-undefined
[5]  
Erofeev VI(2011)Effect of UV activation on acid and catalytiv properties of zeolite-containing catalysts in conversion of gas-condensate straight-run gasolines to high-octane gasolines Russ. J. Appl. Chem. 84 1760-undefined
[6]  
Erofeev VI(1989)Role of Lewis and Brønsted acid sites in zeolites and amorphous aluminosilicates in the formation of condensation products in reactions of propane and propylene Kinet. Catal. 29 796-undefined
[7]  
Adyaeva LV(undefined)undefined undefined undefined undefined-undefined
[8]  
Ryabov YuV(undefined)undefined undefined undefined undefined-undefined
[9]  
Erofeev VI(undefined)undefined undefined undefined undefined-undefined
[10]  
Adyaeva LV(undefined)undefined undefined undefined undefined-undefined