Development of a novel metal hydride–air secondary battery

被引:0
作者
S. Gamburzev
W. Zhang
O. A. Velev
S. Srinivasan
A. J. Appleby
A. Visintin
机构
[1] Texas A&M University System,Center for Electrochemical Systems and Hydrogen Research, Texas Engineering Experiment Station
[2] Universidad Nacional de La Plata,Instituto Nacional de Investigaciones Fisicoqui´mica Teo´ricas y Aplicadas (INIFTA)
[3] Suc. 4-C.C. 16,undefined
来源
Journal of Applied Electrochemistry | 1998年 / 28卷
关键词
metal hydride/air cell; gas diffusion electrode; nickel and cobalt oxides;
D O I
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中图分类号
学科分类号
摘要
A laboratory metal hydride/air cell was evaluated. Charging was via a bifunctional air gas-diffusion electrode. Mixed nickel and cobalt oxides, supported on carbon black and activated carbon, were used as catalysts in this electrode. At 30mAcm−2 in 6m KOH, the air electrode potentials were −0.2V (oxygen reduction) and +0.65V (oxygen evolution) vs Hg/HgO. The laboratory cell was cycled for 50 cycles at the C/2 rate (10mAcm−2). The average discharge/charge voltages of the cell were 0.65 and 1.6V, respectively. The initial capacity of the metal hydride electrode decreased by about 15% after 50 cycles.
引用
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页码:545 / 549
页数:4
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